The attorneys' argument was based largely on the fact that Smith survived a botched attempt to execute him by lethal injection in November 2022.
Smith's petition for a writ of certiorari asked: "Does a second attempt to execute a condemned person following a single, cruelly willful attempt to execute that same person violate the prohibition against cruel and unusual punishments under the Eighth and 14th amendments to the United States Constitution?"
A separate challenge by Smith to the use of nitrogen gas in his execution is pending before the 11th U.S. Circuit Court of Appeals.
Two other states, Mississippi and Oklahoma, have approved the use of nitrogen gas for executions. States have scrambled to find alternative means of killing condemned inmates after the European Union banned the sale and export of lethal injection drugs in 2011.
Earlier this month, Ravina Shamdasani, a spokesperson for the United Nations Office of the High Commissioner for Human Rights, warned that the U.S. may be violating the Covenant on Civil and Political Rights and the Convention Against Torture and Other Cruel, Inhuman, or Degrading Treatment or Punishment by allowing Smith's execution by nitrogen asphyxia.
Shamdasani noted that the American Veterinary Medical Association recommends sedating animals before euthanizing them with nitrogen—a step that is not included in Alabama's protocol.
In addition to concerns over the method of Smith's impending execution, advocates have also pointed to flaws in his sentencing process. The jury that convicted him in 1996 voted 11-1 to recommend a sentence of life imprisonment without the possibility of parole, but a judge invoked a since-outlawed rule to override the jurors.
Rights groups urged Alabama's Republican governor to halt Smith's execution—a move she declined in 2022.
"The death penalty is the ultimate cruel, inhuman, and degrading punishment, and we urge Alabama Gov. Kay Ivey to use her clemency power to stop the execution of Kenneth Smith before it's too late," Amnesty International implored Wednesday.
Abraham Bonowitz, co-founder of the abolitionist group Death Penalty Action, called Wednesday "a shameful day for our country."
"The discussion that is missing in all of this hubbub around nitrogen hypoxia is the mental torture of a second execution attempt," he added. "That, and the fact that if Kenny Smith were on trial today, he could not be sentenced to death at all because his jury was not unanimous regarding his sentence. Jury overrides were outlawed in Alabama in 2017. Alabama's capital punishment system as a whole is broken and cannot be trusted to get it right."